TEL: (212) 752-2020
FAX: (212) 821 0025
733 Third Ave. FL 20
New York, NY
10017 USA

SAFETY DATA SHEET



1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifiers

Product name

:

Diisononyl phthalate

CAS-No.

:

28553-12-0

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

: Laboratory chemicals, Synthesis of substances

1.3 Details of the supplier of the safety data sheet

Distributor

: Continental Industries Group, Inc.

 

733

Third Avenue Fl. 20

 

Tel:

212-752-2020

 

New York, NY 10017

 

USA

1.4 Emergency telephone number

Chemtel Phone #

: 1-800-255-3924

International Phone #

: +01-813-248-0585

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Carcinogenicity (Category 2), H351 Reproductive toxicity (Category 1B), H360

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal word

Danger

Hazard statement(s)

 

H351

Suspected of causing cancer.

H360

May damage fertility or the unborn child.

Precautionary statement(s)

 

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and

 

understood.

P280

Wear protective gloves/ protective clothing/ eye protection/ face

 

protection.

P308 + P313

IF exposed or concerned: Get medical advice/ attention.

P405

Store locked up.

P501

Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

 

 

 

 

 

Formula

:

C26H42O4

 

 

Molecular weight

:

418.61 g/mol

 

 

Hazardous components

 

 

 

 

 

Component

 

 

Classification

Concentration

bis(2-Ethylhexyl) phthalate Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)

CAS-No.

117-81-7

Repr. 1B; H360

>= 0.1 - < 1 %

EC-No.

204-211-0

 

 

Index-No.

607-317-00-9

 

 

 

 

 

 

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

No data available

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.

For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid inhalation of vapour or mist. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Storage class (TRGS 510): Non Combustible Liquids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Component

CAS-No.

Value

Control

 

Basis

 

 

 

parameters

 

 

bis(2-Ethylhexyl)

117-81-7

TWA

5.000000

 

USA. ACGIH Threshold Limit Values

phthalate

 

 

mg/m3

 

(TLV)

 

Remarks

Lower Respiratory Tract irritation

 

 

Confirmed animal carcinogen with unknown relevance to humans

 

 

TWA

5.000000

 

USA. NIOSH Recommended

 

 

 

mg/m3

 

Exposure Limits

 

 

Potential Occupational Carcinogen

 

 

See Appendix A

 

 

 

 

ST

10.000000

 

USA. NIOSH Recommended

 

 

 

mg/m3

 

Exposure Limits

 

 

Potential Occupational Carcinogen

 

 

See Appendix A

 

 

 

 

TWA

5.000000

 

USA. Occupational Exposure Limits

 

 

 

mg/m3

 

(OSHA) - Table Z-1 Limits for Air

 

 

 

 

 

Contaminants

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION cont' d

Body Protection

Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi- purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a)

Appearance

Form: liquid

b)

Odour

No data available

c)

Odour Threshold

No data available

d)

pH

No data available

e)

Melting point/freezing

No data available

 

point

 

f)

Initial boiling point and

No data available

 

boiling range

 

g)

Flash point

No data available

h)

Evaporation rate

No data available

i)

Flammability (solid, gas)

No data available

j)

Upper/lower

No data available

 

flammability or

 

 

explosive limits

 

k)

Vapour pressure

No data available

l)

Vapour density

No data available

m)

Relative density

0.972 g/mL at 25 °C (77 °F)

n)

Water solubility

No data available

o)

Partition coefficient: n-

No data available

 

octanol/water

 

p)

Auto-ignition

No data available

 

temperature

 

q)

Decomposition

No data available

 

temperature

 

r)

Viscosity

No data available

s)

Explosive properties

No data available

t)

Oxidizing properties

No data available

9.2 Other safety information

No data available

10. STABILITY AND REACTIVITY

10.1 Reactivity

No data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

No data available

10.5 Incompatible materials

No data available

10.6 Hazardous decomposition products

Other decomposition products - No data available In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - > 10,000 mg/kg (OECD Test Guideline 401)

LC50 Inhalation - Rat - 4 h - > 4.4 mg/l LD50 Dermal - Rabbit - > 3,160 mg/kg No data available

Skin corrosion/irritation

Skin - Rabbit

Result: No skin irritation - 4 h (OECD Test Guideline 404)

Serious eye damage/eye irritation

Eyes - Rabbit

Result: No eye irritation (OECD Test Guideline 405)

Respiratory or skin sensitisation

Buehler Test - Guinea pig

Result: Does not cause skin sensitisation. (Directive 67/548/EEC, Annex V, B.6.)

Germ cell mutagenicity

Ames test

S. typhimurium

Result: negative

Carcinogenicity

IARC:

2B - Group 2B: Possibly carcinogenic to humans (bis(2-Ethylhexyl) phthalate)

NTP:

Reasonably anticipated to be a human carcinogen (bis(2-Ethylhexyl) phthalate)

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

No data available

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Kidney - (bis(2-Ethylhexyl) phthalate)

12. ECOLOGICAL INFORMATION

12.1 Toxicity

 

 

Toxicity to fish

semi-static test LC50 - Danio rerio (zebra fish) - > 102 mg/l

- 96 h

 

(Directive 67/548/EEC, Annex V, C.1.)

 

Toxicity to daphnia and

Growth inhibition - Daphnia magna (Water flea) - > 74 mg/l

- 48 h

other aquatic

(Directive 67/548/EEC, Annex V, C.2.)

 

invertebrates

 

 

Toxicity to algae

static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) - >

 

88 mg/l - 72 h

 

 

(Directive 67/548/EEC, Annex V, C.3.)

 

12.2 Persistence and degradability

Biodegradability

aerobic - Exposure time 28 d

 

Result: 81 % - Readily biodegradable

 

(Directive 67/548/EEC Annex V, C.4.C.)

12.3 Bioaccumulative potential

Bioaccumulation

Oncorhynchus mykiss (rainbow trout)

Bioconcentration factor (BCF): < 3

Remarks: Bioaccumulation is unlikely.

12.4 Mobility in soil

Adsorbs on soil.

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

No data available

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION DOT (US) Not dangerous goods

IMDG Not dangerous goods

IATA

Not dangerous goods

 

15. REGULATORY INFORMATION

SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

The following components are subject to reporting levels established by SARA Title III, Section 313:

 

CAS-No.

Revision Date

bis(2-Ethylhexyl) phthalate

117-81-7

2007-07-01

SARA 311/312 Hazards

 

 

Chronic Health Hazard

 

 

Massachusetts Right To Know Components

 

 

 

CAS-No.

Revision Date

bis(2-Ethylhexyl) phthalate

117-81-7

2007-07-01

Pennsylvania Right To Know Components

 

 

 

CAS-No.

Revision Date

Diisononyl phthalate

28553-12-0

 

bis(2-Ethylhexyl) phthalate

117-81-7

2007-07-01

New Jersey Right To Know Components

 

 

 

CAS-No.

Revision Date

Diisononyl phthalate

28553-12-0

 

bis(2-Ethylhexyl) phthalate

117-81-7

2007-07-01

California Prop. 65 Components

 

 

WARNING! This product contains a chemical known to the

CAS-No.

Revision Date

State of California to cause cancer.

117-81-7

2009-02-01

bis(2-Ethylhexyl) phthalate

 

 

Diisononyl phthalate

28553-12-0

2013-12-20

WARNING: This product contains a chemical known to the

CAS-No.

Revision Date

State of California to cause birth defects or other reproductive

117-81-7

2009-02-01

harm.

 

 

bis(2-Ethylhexyl) phthalate

 

 

16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

H351

Suspected of causing cancer.

H360

May damage fertility or the unborn child.

Repr.

Reproductive toxicity

HMIS Rating

 

 

Health hazard:

 

0

Chronic Health Hazard:

*

Flammability:

 

0

Physical Hazard

 

0

NFPA Rating

 

 

Health hazard:

 

0

Fire Hazard:

 

0

Reactivity Hazard:

 

0

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Continental Industries Group, Inc. shall not be held liable for any damage resulting from handling or from contact with the above product.