TEL: (212) 752-2020
FAX: (212) 821 0025
733 Third Ave. FL 20
New York, NY
10017 USA

SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifiers

Product name

:

Isobornyl acrylate

CAS-No.

:

5888-33-5

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

: Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Distributor

: Continental Industries Group, Inc.

 

733 Third Avenue Fl. 20

 

New York, NY 10017

 

USA

1.4 Emergency telephone number

Chemtel Phone #

: 1-800-255-3924

International Phone #

: +01-813-248-0585

Contract #

: MIS0001728

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319

Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Acute aquatic toxicity (Category 2), H401

Chronic aquatic toxicity (Category 2), H411

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal word

Warning

Hazard statement(s)

 

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

H411

Toxic to aquatic life with long lasting effects.

Precautionary statement(s)

 

P261

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P264

Wash skin thoroughly after handling.

P271

Use only outdoors or in a well-ventilated area.

P273

Avoid release to the environment.

P280

 

Wear protective gloves/ eye protection/ face protection.

P302

+ P352

IF ON SKIN: Wash with plenty of soap and water.

P304

+ P340

IF INHALED: Remove victim to fresh air and keep at rest in a position

 

 

comfortable for breathing.

P305

+ P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove

 

 

contact lenses, if present and easy to do. Continue rinsing.

P312

 

Call a POISON CENTER or doctor/ physician if you feel unwell.

P321

 

Specific treatment (see supplemental first aid instructions on this label).

P332

+ P313

If skin irritation occurs: Get medical advice/ attention.

P337

+ P313

If eye irritation persists: Get medical advice/ attention.

P362

 

Take off contaminated clothing and wash before reuse.

P391

 

Collect spillage.

P403

+ P233

Store in a well-ventilated place. Keep container tightly closed.

P405

 

Store locked up.

P501

 

Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

 

 

 

 

 

Formula

:

C13H20O2

 

 

Molecular Weight

:

208.3 g/mol

 

 

CAS-No.

: 5888-33-5

 

 

 

EC-No.

: 227-561-6

 

 

 

Index-No.

:

607-133-00-9

 

 

 

Hazardous components

 

 

 

 

 

Component

 

 

Classification

Concentration

 

Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

 

 

 

 

 

Skin Irrit. 2; Eye Irrit. 2A;

90 - 100 %

 

 

 

 

STOT SE 3; Aquatic Acute 2;

 

 

 

 

 

Aquatic Chronic 2; H315,

 

 

 

 

 

H319, H335, H411

 

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed no data available

5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information no data available

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.

For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Light sensitive.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Body Protection

impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi- purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a)

Appearance

Form: liquid

b)

Odour

no data available

c)

Odour Threshold

no data available

d)

pH

no data available

e)

Melting point/freezing

no data available

 

point

 

f)

Initial boiling point and

119 - 121 °C (246 - 250 °F) at 20 hPa (15 mmHg)

 

boiling range

 

g)

Flash point

97 °C (207 °F) - closed cup

h)

Evapouration rate

no data available

i)

Flammability (solid, gas)

no data available

j)

Upper/lower

no data available

 

flammability or

 

 

explosive limits

 

k)

Vapour pressure

no data available

l)

Vapour density

no data available

m)

Relative density

0.986 g/cm3

n)

Water solubility

no data available

o)

Partition coefficient: n-

no data available

 

octanol/water

 

p)

Auto-ignition

no data available

 

temperature

 

q)

Decomposition

no data available

 

temperature

 

r)

Viscosity

no data available

s)

Explosive properties

no data available

t)

Oxidizing properties

no data available

9.2 Other safety information no data available

10. STABILITY AND REACTIVITY

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions no data available

10.4 Conditions to avoid no data available

10.5 Incompatible materials

Oxidizing agents, Reducing agents, PeroxidesStrong oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products - no data available In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - rat - 4,890 mg/kg

Remarks: Behavioral:Tremor. Lungs, Thorax, or Respiration:Dyspnea. Skin and Appendages: Other: Hair. Inhalation: no data available

LD50 Dermal - rabbit - > 5,000 mg/kg no data available

Skin corrosion/irritation

Moderate skin irritation

Serious eye damage/eye irritation

Moderate eye irritation

Respiratory or skin sensitisation no data available

Germ cell mutagenicity no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as

 

probable, possible or confirmed human carcinogen by IARC.

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

carcinogen or potential carcinogen by ACGIH.

NTP:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

known or anticipated carcinogen by NTP.

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity no data available

no data available

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure no data available

Aspiration hazard no data available

Additional Information

RTECS: UD3940000

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

12. ECOLOGICAL INFORMATION

12.1 Toxicity

Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 1.1 mg/l - 48 h other aquatic

invertebrates

12.2 Persistence and degradability no data available

12.3 Bioaccumulative potential no data available

12.4 Mobility in soil no data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long lasting effects.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

DOT (US)

Not dangerous goods

IMDG

 

 

 

UN number: 3082

Class: 9

Packing group: III

EMS-No: F-A, S-F

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Exo-1,7,7- trimethylbicyclo[2.2.1]hept-2-yl acrylate)

Marine pollutant: Marine pollutant

IATA

 

 

UN number: 3082

Class: 9

Packing group: III

Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate)

Further information

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.

15. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Acute Health Hazard

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

 

 

 

CAS-No.

Revision Date

Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

5888-33-5

 

New Jersey Right To Know Components

 

 

 

CAS-No.

Revision Date

Exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate

5888-33-5

 

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

Aquatic Acute

Acute aquatic toxicity

Aquatic Chronic

Chronic aquatic toxicity

Eye Irrit.

Eye irritation

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

H401

Toxic to aquatic life.

H411

Toxic to aquatic life with long lasting effects.

HMIS Rating

 

Health hazard:

2

Chronic Health Hazard:

Flammability:

1

Physical Hazard

0

NFPA Rating

 

Health hazard:

2

Fire Hazard:

1

Reactivity Hazard:

0

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Continental Industries Group, Inc. shall not be held liable for any damage resulting from handling or from contact with the above product.

Details of the supplier of the safety data sheet

Distributor

:

Continental Industries Group, Inc.

 

 

733 Third Avenue Fl. 20

 

 

New York, NY 10017

 

 

USA

Emergency telephone number

 

Chemtel Phone #

:

1-800-255-3924

International Phone #

:

+01-813-248-0585

Contract #

:

MIS0001728

GHS Label elements, including precautionary statements

Pictogram

Signal word

Warning

Hazard statement(s)

 

H315

 

Causes skin irritation.

H319

 

Causes serious eye irritation.

H335

 

May cause respiratory irritation.

H411

 

Toxic to aquatic life with long lasting effects.

Precautionary statement(s)

 

P261

 

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.

P264

 

Wash skin thoroughly after handling.

P271

 

Use only outdoors or in a well-ventilated area.

P273

 

Avoid release to the environment.

P280

 

Wear protective gloves/ eye protection/ face protection.

P302

+ P352

IF ON SKIN: Wash with plenty of soap and water.

P304

+ P340

IF INHALED: Remove victim to fresh air and keep at rest in a position

 

 

comfortable for breathing.

P305

+ P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove

 

 

contact lenses, if present and easy to do. Continue rinsing.

P312

 

Call a POISON CENTER or doctor/ physician if you feel unwell.

P321

 

Specific treatment (see supplemental first aid instructions on this label).

P332

+ P313

If skin irritation occurs: Get medical advice/ attention.

P337

+ P313

If eye irritation persists: Get medical advice/ attention.

P362

 

Take off contaminated clothing and wash before reuse.

P391

 

Collect spillage.

P403

+ P233

Store in a well-ventilated place. Keep container tightly closed.

P405

 

Store locked up.

P501

 

Dispose of contents/ container to an approved waste disposal plant.