1.
PRODUCT AND COMPANY IDENTIFICATION
1.1
Product identifiers
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Product name
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:
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Isobornyl methacrylate
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CAS-No.
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:
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7534-94-3
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1.2
Relevant identified uses of the substance or mixture and uses advised against
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Identified uses
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: Laboratory chemicals, Manufacture of substances
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1.3
Details of the supplier of the safety data sheet
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Distributor
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: Continental Industries Group, Inc.
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733
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Third Avenue Fl. 20
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Tel:
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212-752-2020
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New York, NY 10017
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USA
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1.4
Emergency telephone number
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Chemtel Phone #
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: 1-800-255-3924
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International Phone #
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: +01-813-248-0585
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2. HAZARDS IDENTIFICATION
2.1
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 3), H412
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2
GHS Label elements, including precautionary statements
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Pictogram
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none
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Signal word
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none
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Hazard statement(s)
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H401
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Toxic to aquatic life.
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H412
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Harmful to aquatic life with long lasting effects.
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Precautionary statement(s)
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P273
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Avoid release to the environment.
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P501
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Dispose of contents/ container to an approved waste disposal plant.
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2.3
Hazards not otherwise classified (HNOC) or not covered by GHS
- none
3. COMPOSITION/INFORMATION ON INGREDIENTS
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3.1 Substances
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Formula
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:
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C14H22O2
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Molecular weight
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:
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222.33 g/mol
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CAS-No.
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: 7534-94-3
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EC-No.
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:
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231-403-1
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Hazardous components
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Component
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Classification
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Concentration
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exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate
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Aquatic Acute 2; Aquatic
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<= 100 %
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Chronic 3; H401, H412
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For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3
Indication of any immediate medical attention and special treatment needed
No data available
5. FIREFIGHTING MEASURES
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
Special hazards arising from the substance or mixture
Carbon oxides
5.3
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4
Further information
No data available
6. ACCIDENTAL RELEASE MEASURES
6.1
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
6.4
Reference to other sections
For disposal see section 13.
7. HANDLING AND STORAGE
7.1
Precautions for safe handling
For precautions see section 2.2.
7.2
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Combustible liquids
7.3
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1
Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi- purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1
Information on basic physical and chemical properties
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a)
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Appearance
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Form: liquid
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Colour: colourless
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b)
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Odour
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ester-like
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c)
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Odour Threshold
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No data available
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d)
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pH
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No data available
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e)
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Melting point/freezing
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Melting point/range: -93.99 °C (-137.18 °F) at 1,013 hPa (760 mmHg)
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point
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f)
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Initial boiling point and
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127 - 129 °C (261 - 264 °F) at 20 hPa (15 mmHg)
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boiling range
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g)
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Flash point
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114 °C (237 °F) - Pensky-Martens closed cup - ASTM D 93
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h)
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Evaporation rate
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No data available
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i)
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Flammability (solid, gas)
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No data available
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j)
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Upper/lower
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No data available
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flammability or
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explosive limits
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k)
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Vapour pressure
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No data available
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l)
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Vapour density
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No data available
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m)
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Relative density
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0.983 g/cm3
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n)
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Water solubility
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5.44 g/l at 20 °C (68 °F) - OECD Test Guideline 105 - slightly soluble
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o)
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Partition coefficient: n-
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log Pow: 5.09
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octanol/water
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p)
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Auto-ignition
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385 °C (725 °F) at 1,013 hPa (760 mmHg)
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temperature
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q)
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Decomposition
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No data available
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temperature
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r)
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Viscosity
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8.39 mm2/s at 20 °C (68 °F) -
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s)
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Explosive properties
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No data available
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t)
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Oxidizing properties
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No data available
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9.2
Other safety information
No data available
10. STABILITY AND REACTIVITY
10.1
Reactivity
No data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
Possibility of hazardous reactions
No data available
10.4
Conditions to avoid
No data available
10.5
Incompatible materials
Oxidizing agents, Reducing agents, Peroxides
10.6
Hazardous decomposition products
Other decomposition products - No data available In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION
11.1
Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - > 2,000 mg/kg Inhalation: No data available
Dermal: No data available No data available
Skin corrosion/irritation
Skin - Rabbit
Result: Mild skin irritation - 4 h (OECD Test Guideline 404)
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
Maximisation Test (GPMT) - Guinea pig Result: Does not cause skin sensitisation. (OECD Test Guideline 406)
Germ cell mutagenicity
Ames test
S. typhimurium Result: negative
Carcinogenicity
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IARC:
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No component of this product present at levels greater than or equal to 0.1% is identified as
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probable, possible or confirmed human carcinogen by IARC.
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ACGIH:
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No component of this product present at levels greater than or equal to 0.1% is identified as a
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carcinogen or potential carcinogen by ACGIH.
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NTP:
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No component of this product present at levels greater than or equal to 0.1% is identified as a
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known or anticipated carcinogen by NTP.
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OSHA:
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No component of this product present at levels greater than or equal to 0.1% is identified as a
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carcinogen or potential carcinogen by OSHA.
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Reproductive toxicity
No data available
Reproductive toxicity - Rat - male and female - Oral
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
12. ECOLOGICAL INFORMATION
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12.1 Toxicity
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Toxicity to fish
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semi-static test LC50 - Danio rerio (zebra fish) - 1.79 mg/l - 96 h
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(OECD Test Guideline 203)
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Toxicity to daphnia and
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semi-static test EC50 - Daphnia magna (Water flea) - > 2.57 mg/l - 48 h
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other aquatic
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(OECD Test Guideline 202)
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invertebrates
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Toxicity to algae
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static test EC50 - Pseudokirchneriella subcapitata - 2.28 mg/l - 72 h
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(OECD Test Guideline 201)
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12.2
Persistence and degradability
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Biodegradability
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aerobic - Exposure time 28 d
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Result: 70 % - Readily biodegradable
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(OECD Test Guideline 310)
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12.3
Bioaccumulative potential
No data available
12.4
Mobility in soil
No data available
12.5
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6
Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life.
13. DISPOSAL CONSIDERATIONS
13.1
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
No SARA Hazards
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
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Pennsylvania Right To Know Components
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CAS-No.
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Revision Date
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exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate
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7534-94-3
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New Jersey Right To Know Components
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CAS-No.
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Revision Date
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exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate
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7534-94-3
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California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
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Aquatic Acute
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Acute aquatic toxicity
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Aquatic Chronic
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Chronic aquatic toxicity
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H401
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Toxic to aquatic life.
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H412
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Harmful to aquatic life with long lasting effects.
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HMIS Rating
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Health hazard:
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0
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Chronic Health Hazard:
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Flammability:
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1
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Physical Hazard
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0
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NFPA Rating
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Health hazard:
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0
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Fire Hazard:
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1
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Reactivity Hazard:
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0
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Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Continental Industries Group, Inc. shall not be held liable for any damage resulting from handling or from contact with the above product.