TEL: (212) 752-2020
FAX: (212) 821 0025
733 Third Ave. FL 20
New York, NY
10017 USA

SAFETY DATA SHEET

1. PRODUCT AND COMPANY IDENTIFICATION

1.1 Product identifiers

Product name

:

Isobornyl methacrylate

CAS-No.

:

7534-94-3

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses

: Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Distributor

: Continental Industries Group, Inc.

 

733

Third Avenue Fl. 20

 

Tel:

212-752-2020

 

New York, NY 10017

 

USA

1.4 Emergency telephone number

Chemtel Phone #

: 1-800-255-3924

International Phone #

: +01-813-248-0585

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 3), H412

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

none

Signal word

none

Hazard statement(s)

 

H401

Toxic to aquatic life.

H412

Harmful to aquatic life with long lasting effects.

Precautionary statement(s)

 

P273

Avoid release to the environment.

P501

Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

 

 

Formula

:

C14H22O2

Molecular weight

:

222.33 g/mol

CAS-No.

: 7534-94-3

EC-No.

:

231-403-1

Hazardous components

Component

Classification

Concentration

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate

 

 

Aquatic Acute 2; Aquatic

<= 100 %

 

Chronic 3; H401, H412

 

For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES

4.1 Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

No data available

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Combustible liquids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Body Protection

impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi- purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a)

Appearance

Form: liquid

 

 

Colour: colourless

b)

Odour

ester-like

c)

Odour Threshold

No data available

d)

pH

No data available

e)

Melting point/freezing

Melting point/range: -93.99 °C (-137.18 °F) at 1,013 hPa (760 mmHg)

 

point

 

f)

Initial boiling point and

127 - 129 °C (261 - 264 °F) at 20 hPa (15 mmHg)

 

boiling range

 

g)

Flash point

114 °C (237 °F) - Pensky-Martens closed cup - ASTM D 93

h)

Evaporation rate

No data available

i)

Flammability (solid, gas)

No data available

j)

Upper/lower

No data available

 

flammability or

 

 

explosive limits

 

k)

Vapour pressure

No data available

l)

Vapour density

No data available

m)

Relative density

0.983 g/cm3

n)

Water solubility

5.44 g/l at 20 °C (68 °F) - OECD Test Guideline 105 - slightly soluble

o)

Partition coefficient: n-

log Pow: 5.09

 

octanol/water

 

p)

Auto-ignition

385 °C (725 °F) at 1,013 hPa (760 mmHg)

 

temperature

 

q)

Decomposition

No data available

 

temperature

 

r)

Viscosity

8.39 mm2/s at 20 °C (68 °F) -

s)

Explosive properties

No data available

t)

Oxidizing properties

No data available

9.2 Other safety information

No data available

10. STABILITY AND REACTIVITY

10.1 Reactivity

No data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

No data available

10.5 Incompatible materials

Oxidizing agents, Reducing agents, Peroxides

10.6 Hazardous decomposition products

Other decomposition products - No data available In the event of fire: see section 5

11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - > 2,000 mg/kg Inhalation: No data available

Dermal: No data available No data available

Skin corrosion/irritation

Skin - Rabbit

Result: Mild skin irritation - 4 h (OECD Test Guideline 404)

Serious eye damage/eye irritation

No data available

Respiratory or skin sensitisation

Maximisation Test (GPMT) - Guinea pig Result: Does not cause skin sensitisation. (OECD Test Guideline 406)

Germ cell mutagenicity

Ames test

S. typhimurium Result: negative

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as

 

probable, possible or confirmed human carcinogen by IARC.

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

carcinogen or potential carcinogen by ACGIH.

NTP:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

known or anticipated carcinogen by NTP.

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

 

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

No data available

Reproductive toxicity - Rat - male and female - Oral

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

12. ECOLOGICAL INFORMATION

12.1 Toxicity

 

Toxicity to fish

semi-static test LC50 - Danio rerio (zebra fish) - 1.79 mg/l - 96 h

 

(OECD Test Guideline 203)

Toxicity to daphnia and

semi-static test EC50 - Daphnia magna (Water flea) - > 2.57 mg/l - 48 h

other aquatic

(OECD Test Guideline 202)

invertebrates

 

Toxicity to algae

static test EC50 - Pseudokirchneriella subcapitata - 2.28 mg/l - 72 h

 

(OECD Test Guideline 201)

12.2 Persistence and degradability

Biodegradability

aerobic - Exposure time 28 d

 

Result: 70 % - Readily biodegradable

 

(OECD Test Guideline 310)

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life.

13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

14. TRANSPORT INFORMATION

DOT (US)

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

15. REGULATORY INFORMATION

SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

No SARA Hazards

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

 

 

 

CAS-No.

Revision Date

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate

7534-94-3

 

New Jersey Right To Know Components

 

 

 

CAS-No.

Revision Date

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl methacrylate

7534-94-3

 

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

16. OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

Aquatic Acute

Acute aquatic toxicity

Aquatic Chronic

Chronic aquatic toxicity

H401

Toxic to aquatic life.

H412

Harmful to aquatic life with long lasting effects.

HMIS Rating

 

Health hazard:

0

Chronic Health Hazard:

Flammability:

1

Physical Hazard

0

NFPA Rating

 

Health hazard:

0

Fire Hazard:

1

Reactivity Hazard:

0

Further information

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Continental Industries Group, Inc. shall not be held liable for any damage resulting from handling or from contact with the above product.